ASTM A193 Specifications

Specification for Alloy and Stainless Steel Fasteners for High-Temperature, High-Pressure, and Special Applications

The specification gives the requirements for alloy and stainless steel fasteners to be applied in pressure vessels, valves, flanges, fittings, and other equipment that are subjected to high temperatures or pressures, as well as in specialised applications. Additional specifications of bolting can be found in ASTM A962/A962M.

The fastener material can be provided in hot-worked bars or wire that is optionally processed, e.g., centerless ground or cold drawn. Austenitic stainless steels may be treated by a carbide solution treatment or strain hardening, as well as by a combination of a carbide solution treatment and strain hardening. In the case of strain-hardened austenitic steel, it is necessary that the buyer peruses Appendix 1.

The specification covers a set of grades, which are both ferritic and austenitic stainless steel (B5, B8, etc.). Choice of an adequate grade lies on variables such as design requirements, service conditions, and mechanical and high-temperature performance.

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Chemical Requirements (Composition, percent)

Each alloy shall conform to the chemical composition requirements prescribed in the table below:

Ferritic Steels

Grade Description & UNS Designation C Mn P S Si Cr Ni Mo Cu Nb Ti V Al N
B5 5% Chromium 0.10 min 1.00 0.040 0.030 1.00 4.0–6.0 ... 0.40–0.65 ... ... ... ... ... ...
B6 12%
B6X Chromium (410), S41000 0.08–0.15 1.00 0.040 0.030 1.00 115–13.5 ... ... ... ... ... ... ... ...
B7 / B7M Chromium Molybdenum 0.38–0.48 0.75–1.00 0.035 0.040 0.15–0.35 0.80–1.10 ... 0.15–0.25 ... ... ... ... ... ...
B16 Chromium-molybdenum-vanadium 0.36–0.47 0.45–0.70 0.035 0.040 0.15–0.35 0.80–1.15 ... 0.50–0.65 ... ... ... 0.05–0.35 0.015 ...

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Austenitic Steels

Grade Description C Mn P S Si Cr Ni Mo Cu Nb Ti V Al N
B8 / B8A 304, S30400 0.08 2.00 0.045 0.030 1.00 18.0–20.0 8.0–11.0 ... ... ... ... ... ... ...
B8C / B8CA 347, S34700 0.08 2.00 0.045 0.030 1.00 17.0–19.0 9.0–12.0 ... ... 10×C to 1.10 ... ... ... ...
B8M / B8MA / B8M2 / B8M3 316, S31600 0.08 2.00 0.045 0.030 1.00 16.0–18.0 10.0–14.0 2.00–3.00 ... ... ... ... ... ...
B8P / B8PA S30500 0.12 2.00 0.045 0.030 1.00 17.0–19.0 11.0–13.0 ... ... ... ... ... ... ...
B8N / B8NA 304N, S30451 0.08 2.00 0.045 0.030 1.00 18.0–20.0 8.0–11.0 ... ... ... ... ... ... 0.10–0.16
B8MN / B8MNA 316N, S31651 0.08 2.00 0.045 0.030 1.00 16.0–18.0 10.0–13.0 2.00–3.00 ... ... ... ... ... 0.10–0.16
B8MLCuN / B8MLCuNA S31254 0.020 1.00 0.030 0.010 0.80 19.5–20.5 6.0–6.5 0.50–1.00 ... ... ... ... ... 0.18–0.25
B8T / B8TA 321, S32100 0.08 2.00 0.045 0.030 1.00 17.0–19.0 9.0–12.0 ... ... 5×(C+N) to 0.70 ... ... 0.10 ...
B8R / B8RA S20910 0.06 4.0–6.0 0.045 0.030 1.00 20.5–23.5 11.5–13.5 1.50–3.00 ... 0.10–0.30 ... 0.10–0.30 ... 0.20–0.40
B8S / B8SA S21800 0.10 7.0–9.0 0.060 0.030 3.5–4.5 16.0–18.0 8.0–9.0 ... ... ... ... ... ... 0.08–0.18
B8LN / B8LNA S30453 0.030 2.00 0.045 0.030 1.00 18.0–20.0 8.0–11.0 ... ... ... ... ... ... 0.10–0.16
B8MLN / B8MLNA S31653 0.030 2.00 0.045 0.030 1.00 16.0–18.0 10.0–13.0 2.00–3.00 ... ... ... ... ... 0.10–0.16
B8CLN / B8CLNA 347LN, S34751 0.005–0.020 2.00 0.045 0.030 1.00 17.0–19.0 9.0–13.0 ... ... 0.20–0.50; 15×C, min ... ... ... 0.06–0.10
B8CLNCuB / B8CLNCuBA S34752 0.005–0.020 2.00 0.035 0.010 0.60 17.0–19.0 10.0–13.0 0.0–13.0 0.0–13.0 0.20–0.50; 15×C, min ... ... ... 0.06–0.12
B8ML4CuN / B8ML4CuNA S31730 0.030 2.00 0.040 0.010 1.00 17.0–19.0 15.0–16.5 3.0–4.0 4.0–5.0 ... ... ... ... 0.045

Note:

  • A Values are maximum except where a range or a minimum is represented. In the case of ellipses in this table, no requirement exists and the element does not need to be established and reported. The deliberate incorporation of Bi, Se, Te and Pb is not allowed.
  • B Typical compositions of steel used in this grade are 4140, 4142, 4145, 4140H, 4142H and 4145H
  • C Maximum carbon content 0.50% (maximum) For bar sizes larger than 1/4 in. [90 mm] inclusive. In the B7M grade, a minimum carbon of 0.28% is allowed, as long as the necessary tensile properties are obtained in the sizes of the sections involved, the use of AISI 4130 or 4130H are admissible.
  • D Total of solvents and insolvents.
  • E Columbium and Niobium are alternate names for element 41 in the Periodic Table of the Elements.
  • F For S34752 -Boron content will be 0.001-0.005 both in heat and product analysis.

Heat Treatment - Ferritic Steels

During rolling or forging, ferritic steels are supposed to be left to cool at temperatures which are below the cooling transformation range. The bolting materials are then evenly warmed up to the correct temperature in order to straighten the grain. A group whose reheating is of this type is referred to as a quenching charge. The charge is then extinguished in a liquid medium under relatively homogenous conditions per batch and tempered. The lowest temperature of tempering should not be less than those given in the corresponding tables.

No ferritic grade may be quenched using water when the heat treatment is carried out after either heading or threading.

In the case of B6X material, cold-drawn dimensional control would be stress-relieved after cold drawing by bolting. The lowest permissible stress-relief temperature should be between 100°F (55°C) and the tempering temperature. Post-stress relieving should be followed by mechanical property tests.

The materials (B6 and B6X) will be left at the tempering temperature for at least 1 hour. B6X bolting can be in the condition of being as-rolled-and-tempered. B6X material can be cold worked following heat treatment as long as the end product hardness of the material corresponds to the requirements of a hardness table.

B7 and B7M bolting materials will be quenched in a liquid medium and then tempered. In the case of B7M components, such as bolts, studs, or screws, final heat treatment, which may be the tempering process at a minimum of 1150°F (620°C), shall, in any case, follow all machining and forming operations, including thread rolling and any form of cutting. Hardness testing, nondestructive testing or ultrasonic tensioning of the bolts has to be performed using a surface that has been prepared.

Grade B16 bolting material is to be heated between the temperatures of 1700 and 1750°F (925 to 955°C) and oil quenched. Minimum temperature will be in accordance with the requirements of the corresponding tables.

Heat Treatment - Austenitic Stainless Steels

The austenitic stainless steels will all be subjected to carbide solution treatment (2 para -5 para based on the requirements of each category). Classes 1, 1B, 1C (B8R, B8S only), 2, 2B and 2C may be used on bar, wire and finished bolt components. Bolting components that have been finished may be covered by Class 1A (all grades) or Class 1C (grades B8RA and B8SA only). Class 1D is limited to bar and wire and finished bolting components which are machined directly out of Class 1D bar or wire and which have not undergone any subsequent hot or cold working.

Class 1 and 1B, and Class 1C Grades B8R and B8S: Following rolling of the bar, forging, or heading, both hot and cold, bolting material shall be heated to an ambient temperature and maintained a sufficient time at a temperature in which the chromium carbide will go into solution and then cooled at a rate which will avoid the formation of the carbide.

Class 1D: Rolled or forged grades B8, B8M, B8P, B8LN, B8MLN, B8CLNCuB, B8N, B8MN, B8R, and B8S bars shall be cooled quickly following hot working but when the temperature is not below 1750°C [955°C] so as to leave grain boundary carbides in solution. Class 1D will be limited to uses with temperatures below 850 °F [455 °C].

Class 1A and Class 1C Finished bolting components B8RA and B8SA: Components will be heated at ambient temperature, and maintained long enough at a temperature where the carbide of chromium will go to solution, after which it will be cooled at a rate adequate to inhibit the formation of the carbide.

Classes 2, 2B and 2C: Bolting material will be the carbide solution which is treated by heating to ambient temperature and retained for an adequate length of time at the temperature in which the chromium carbide will go into solution, and then at a rate sufficient to prohibit the precipitation of the carbide. After this treatment the bolting material will then be strain hardened to bring about the necessary properties.

If a scale-free bright finish is required; this shall be specified in the purchase order.

Mechanical Properties (Inch Products)

Grade Diameter (in.) Min Tempering Temp (°F) Tensile Strength (ksi) Yield Strength (ksi) Elongation in 4D (%) Reduction of Area (%) Hardness (max)
B5Up to 41100100801650
B6Up to 41100110851550
B6XUp to 411009070165020 HRC
B7≤2.511001251051650321 HBW / 35 HRC
B7>2.5–41100115951650321 HBW / 35 HRC
B7>4–71100100751850321 HBW / 35 HRC
B7M≤41150100801850235 HBW / 99 HRB
B7M>4–71150100751850235 HBW / 99 HRB
B16≤2.512001251051850321 HBW / 35 HRC
B16>2.5–41200110951745321 HBW / 35 HRC
B16>4–81200100851645321 HBW / 35 HRC

Mechanical Properties - Austenitic Stainless Steels

Grade, Diameter, in. Heat Treatment Tensile Strength, min, ksi Yield Strength, min, 0.25% offset ksi Elongation in 4D, min % Reduction of Area, min % Hardness, max
Classes 1 and 10D: BB, B8M, B8BN, B8N, B8CN1, all diameterscarbide solution treated75303050223 HRB W or 85 HRB
Classes 1 and 10D: B8, B8C, B8LC, all diameterscarbide solution treated75303050223 HRB W or 85 HRB
Class 1: B8C, B8T, all diameterscarbide solution treated75303050223 HRB W or 85 HRB
Class 1: B8BA, B8CA, B8CB, B8CN1, B8CA, B8CA1, all diameterscarbide solution treated in finished condition75303050223 HRB W or 85 HRB
Class 1: B8M, B8ML, B8MC, B8MCLn, all diameterscarbide solution treated80353555271 HRB W or 88 HRB
Class 1: B8, B8B, B8C, B8L, all diameterscarbide solution treated75353050223 HRB W or 85 HRB
Class 1B: B8L, B8M, all diameterscarbide solution treated80353045271 HRB W or 88 HRB
Class 1C: B8B, B8BN, B8T, all diameterscarbide solution treated90403060271 HRB W or 88 HRB
Class 2: B8B, B8B, B8T, B8L, D, or undercarbide solution treated105453555312 HRB W or 100 HRB
Class 2: B8M, B8M2, B8M2L, B8M4carbide solution treated and strain hardened115503560312 HRB W or 100 HRB
Class 2B, B8M2, 2 and undercarbide solution treated and strain hardened100403055350 HRB W or 110 HRB
Class 2B: B8M2, B8M2Lcarbide solution treated and strain hardened85353045360 HRB W or 110 HRB

A To satisfy the tensile specifications, Brinnel hardness will be more than 200 HBW (93 HRB).

B Class 1 is solution treated. Class 1A refers to a solution that is treated in the finished state to be resistant to corrosion; the reason is that heat treatment is important as per physical property demands. Class 2 solution hardened and strain hardened. Strain-hardened austenitic steels do not necessarily possess uniform properties across the section, especially in sizes greater than 3/4 in. in diameter.

C Maximum hardness of 241 HBW (100 HRB) is allowed at sizes ⅝ in. in diameter and lower.

D Center (core?) properties can be less than test report values, which are based on 1/2 radius.

Hardness Requirements

The hardness will be in accordance with the requirements in the Tables of Mechanical Requirements. Testing Hardness testing will be conducted in accordance with either Specification A962/A962M or Test Methods E10/E18/F606/F606M.

Grade B7M - The grade will have a maximum hardness of 235 HBW or 99 HRB. The lowest hardness will not be lower than 200 HBW and 93 HRB. This hardness shall be checked by conducting testing of the hardness of each stud or bolt, according to Brinell or Rockwell B. Alternative testing 100% electromagnetic testing may be used to determine hardness provided that it is qualified by sampling by indentation hardness testing. All lots subjected to electromagnetic hardness are to be 100% inspected according to Practice E566. After electromagnetic testing has been completed on the hardness, a selected sample of at least 100 pieces of each steel heat in every lot shall be subjected to indentation hardness tests. All the samples should be as hard as required to allow acceptance of the lot.

In case any single sample falls below or beyond the given maximum or minimum hardness, the lot will be rejected and either reprocessed and retested or indentation hardness tested 100%.

Preparation of the surface to be tested on indentation hardness shall be done in accordance with Test Methods E18. The end of the bolt or stud shall be subjected to hardness tests. In the event that this is not practical, hardness tests will be carried out otherwise.

Nuts

Bolts, studs, and stud bolts shall be furnished with nuts, when specified in the purchase order. Nuts shall conform to Specification A194/A194M.

Bolt Specification Nut Specification Washer Specification
ASTM A193 Grade B5ASTM A194 Grade 3ASTM A36 Mild Steel
ASTM A193 Grade B6ASTM A194 Grade 6ASTM A240 Grade 410
ASTM A193 Grade B7ASTM A194 Grade 2HASTM F436 Type 1
ASTM A193 Grade B7MASTM A194 Grade 2HMASTM F436 Type 1
ASTM A193 Grade B16ASTM A194 Grade 16ASTM F436 Type 1
ASTM A193 Grade B8ASTM A194 Grade 8ASTM A240 Grade 304
ASTM A193 Grade B8MASTM A194 Grade 8MASTM A240 Grade 316
ASTM A193 Grade B8TASTM A194 Grade 8TASTM A240 Grade 321

Marking of Austenitic Steels

Austenitic steel fasteners are classified into classes and grades with defined grade symbols as per ASTM A193.

ClassGradeGrade Symbol
Class 1B8B8
B8CB8C
B8MB8M
B8PB8P
B8PB8P
B8TB8T
B8LNB8F or B8LN
B8MLNB8G or B8MLN
B8CLNB8Y or B8CLN
B8CLNCuBB8CLNCuB
B8ML4CuNB8YY or B8ML4CuN
Class 1AB8AB8A
B8CAB8B or B8CA
B8MAB8D or B8MA
B8PAB8H or B8PA
B8TAB8J or B8TA
B8LNAB8L or B8LNA
B8MLNAB8K or B8MLNA
B8NAB8V or B8MA
B8MNAB8W or B8MNA
B8MLCuNAB9K or B8MLCuNA
B8CLNAB8Z or B8CLNA
B8CLCuBAB8ZA or B8CLCuBA
B8ML4CuNAB8ZZ or B8MLCuNA
Class 1BB8NB8N
B8MNB8Y or B8MN
B8MLCuNB9J or B8MLCuN
Class 1CB8RB9A or B8R
B8RAB9B or B8RA
B8SB9D or B8S
B8SAB9F or B8SA
Class 1DB8B94
B8MB95
B8PB96
B8LNB97
B8MLNB98
B8NB99
B8MNB100
B8RB101
B8SB102
B8CLNB103
B8ML4CuNB104
B8CLNCuBB105
Class 2B8B8SH
B8CB8CSH
B8PB8PSH
B8TB8TSH
B8TB8TSH
B8NB8NSH
B8MB8MSH
B8MNB8YSH
B8MLCuNB8JSH
Class 2BB8M2B9G or B8M2
B8B9
Class 2CB8M3B9H or B8M3

Supplementary Requirements & Appendix

These requirements shall not apply unless specified in the order and in the Ordering Information, in which case the specified tests shall be made before shipment of the product.

S1. High Temperature Tests
Tests to determine high temperature properties shall be made in accordance with Test Methods E21, E139, and E292, and Practices E150 and E151.

S2. Charpy Impact Tests
Charpy impact tests based on the requirements of Specification A320/A320M, shall be made as agreed between the manufacturer and the purchaser. When testing temperatures are as low as those specified in Specification A320/A320M, bolting should be ordered to that specification reference to this specification.

S3. Hardness Testing of Grade B7M
Each Grade B7M bolt or stud shall be tested for hardness by indentation method and shall meet the requirements specified in Tables.

S4. Hardness Testing of Grade B16
For bolts or studs ≤ ½ in. (16 mm) or smaller, the hardness for Grade B16 shall be measured on or near the end of each bolt or stud using one of the methods prescribed in 9.2.1 for the Brinell or Rockwell C test. The hardness shall be in the range 203-319 HBRW or 25-34 HRC.

S5. Product Marking
Bars and manufacturer’s identification symbols shall be applied to one end of studs and to the heads of bolts and screws of all sizes. (If the available area is inadequate, the grade symbol may be marked on one end and the manufacturer’s identification symbol marked on the other end). For bolts and screws smaller than ½ in. (6 mm) in diameter and studs smaller than ½ in. (10 mm) in diameter for any stud, the grade symbol and manufacturer’s identification symbol may be marked with fewer than 3 symbols. The marking shall be a matter of agreement between the purchaser and the manufacturer.

S6. Stress Relieving
A stress-relieving operation shall follow straightening after heat treatment.
The minimum stress relieving temperature shall be 100 °F [55 °C] below the tempering temperature. Tests for mechanical properties shall be performed after stress relieving.

S7. Magnetic Particle Inspection
Bars shall be magnetic particles examined in accordance with Guide E709. Bars with indications of cracks or seams are subject to rejection if the indications extend more than 3% of the diameter into the bar.

S8. Stress-Relaxation Testing
Stress-Relaxation Testing, when required, shall be done in accordance with Test Methods E328. The test shall be performed at 850 °F [454 °C] for a period of 100 h. The initial stress shall be 50 MPa [345 MPa]. The residual stress at 100 h shall be 17 MPa [117 MPa] minimum.

S9. Grain Size Requirements for Non-H Grade Austenitic Steels Used Above 1000°F
For design high temperatures above 1000 °F [540 °C], the material shall have a grain size of No. 7 or coarser as determined by Test Methods E112. The grain size so determined shall be reported on the Certificate of Test.

S10. Hardness Testing of Class 2 Bolting for ASME Applications
The maximum hardness shall be the Rockwell C15 indenture through the thread roots. The hardness shall be taken on an area of at least 1 in. [25 mm] across, prepared by removing threads, and no more material than necessary shall be removed to prepare the flat areas. Hardness determinations shall be at the same frequency as tensile tests.

S11. Thread Forming
Threads shall be formed after heat treatment. Application of this supplemental requirement to grade B7M or the grades listed is prohibited.

S12. Stress Rupture Testing of Grade B16
One test shall be made for each heat treat lot. Testing shall be conducted using a combination test bar in accordance with Test Methods E292. Rupture shall occur in the smooth section of each test specimen. The test shall be conducted at 1100 °F [595 °C] and 20 ksi [140 MPa]. The time shall be continued until the sample ruptures. Rupture life shall be 25 min. Testing is not required on material less than ½ in. [12.7 mm] thick.

S13. When a purchase order for bolting components invokes S12, the grade symbol applied shall be “B16R.”

S14. Purchaser Requirements
It is the purchaser’s responsibility to specify in the purchase order all information required for mechanical testing. Examples of such information include but are not limited to the following:
Reference to the applicable material specification and type, thickness, location, modifications, and hydrogen embrittlement levels.

S15. Magnetic Bolting Components
Bolting components made with zinc shall have ZnM marked after the grade symbol. Bolting components coated with cadmium shall have a CD marked after the grade symbol.

S16. Requirements for Service Temperature Exceeding 1000°F
When bolting materials of Grades B8, B8C, and B8T, are used in service at temperatures exceeding 1000°F, the following shall apply:
Following the carbide solution treatment and cooling, the material shall then be strain hardened to achieve the required properties. The minimum carbon content shall be 0.04 %.
The minimum carbon content shall be above 1000°F and 1950°F followed by quenching in water or rapid cooling by other means.

Appendix

1. STRAIN HARDENING OF AUSTENITIC STEELS
Strain hardening refers to the increment in strength and hardness occasioned by plastic deformation, which occurs below the recrystallization temperature (cold work). It is achieved in austenitic stainless steels by cold drawing to the required finished size by means of either cold drawing or other methods of oversizing bars or wire. Strain hardening properties are what limits the level of strain hardening that can be attained on any alloy. Moreover, the yields of strain that can be generated depend also on the variables of the process, including the total cross-section reduction, the die angle, and the bar size. With bigger diameter bars, plastic deformation will take place mostly in the outer parts of the bar in such a way that the higher the strength and hardness brought about by strain hardness is attainable in the outer parts of the bar. In other words, the lower the bar, the higher the penetration of strain hardening.

And so, mechanical properties of a particular strain hardened bolting part are not only subject to alloy, but also the size of the bar that it is machined out of. The minimum direction of the bar that may be utilized, however, is determined by the setup of the component such that the setup may influence strength of the component.

An example of this is machining a stud of a certain alloy and size out of a smaller diameter bar than a bolt of the same alloy and size since a large diameter bar is needed to fit the head of the bolt. It is therefore likely that the stud will have a higher strength when compared to a similar size bolt in an alloy.

2. COATINGS AND APPLICATION LIMITS
Use of coated bolting components at temperatures above approximately one-half the melting point (Fahrenheit or Celsius) of the coating is not recommended unless consideration is given to the potential for liquid and solid metal embrittlement, or both. The melting point of elemental zinc is approximately 780 °F [415 °C]. Therefore, application of zinc-coated bolting components should be limited to temperatures less than 390 °F [210 °C]. The melting point of cadmium is approximately 600 °F [320 °C]. Therefore, application of cadmium-coated bolting components should be limited to temperatures less than 300 °F [160 °C].