In piping systems like refineries, power plants, and steam systems, bolts will tend to lose their clamping force as temperatures rise, leading to a condition called ‘losing bolt strength.’ The good news is that such a problem can be resolved when the right material is used. Most manufacturers will prefer to use ASTM A193 Gr B16 for such applications, as the alloying elements including chromium, molybdenum, and vanadium in addition to heat treatment make this grade the right choice for bolting applications where bolting degradation can be present due to high temperature conditions.
Unifit Fasteners supplies ASTM A193 Gr B16 bolts and stud bolts in India for the industries that deal with high-temperature applications such as pipeline operations, pressure vessels, valves, boiler systems, petrochemical processes, etc. The next sections will discuss chemical composition, mechanical properties, heat treatment processes, and various standards applicable to the B16 grade.
Related grades: ASTM A193 B7 · A193 B7M (sour service) · Alloy Steel Fasteners hub
Request QuoteASTM A193 Grade B16 is the specification for chromium-molybdenum-vanadium (Cr-Mo-V) alloy steel bolting used in high-temperature, high-pressure service: bolts, studs, nuts, and screws for power plants, refineries, and chemical processing. It is a close relative of the far more common Grade B7. Both start from a 4140-type chromium-molybdenum steel, quenched and tempered. The difference is vanadium, plus a higher tempering temperature, and that difference is entirely about heat.
Below roughly 400 degrees C, B7 and B16 behave much alike and B7's lower cost usually wins. Above it, they diverge sharply. Vanadium stabilises the steel's microstructure against creep, the slow time-dependent deformation that, in a bolt, shows up as stress relaxation: the fastener gradually sheds the preload holding the joint tight. A relaxed bolt means a decompressed gasket, and a decompressed gasket means a leak. B16 is specified precisely where that failure mode is unacceptable, and it holds usable strength up to about 590 degrees C (1100 degrees F).
B16 is available as bolts, screws, and stud bolts in every common configuration, from hex and structural bolts through socket and machine screws to full-threaded, double-end, and continuous-threaded studs, in standard and custom sizes.
Grade B16's chromium-molybdenum-vanadium chemistry gives it corrosion resistance, high-temperature strength, and creep resistance for power, refinery, and high-pressure service.
| Element | Content Range |
|---|---|
| Carbon (C) | 0.36 - 0.47% |
| Manganese (Mn) | 0.45 - 0.70% |
| Phosphorus (P) | 0.035% max |
| Sulfur (S) | 0.040% max |
| Silicon (Si) | 0.15 - 0.35% |
| Chromium (Cr) | 0.80 - 1.15% |
| Molybdenum (Mo) | 0.50 - 0.65% |
| Vanadium (V) | 0.25 - 0.35% |
| Aluminum (Al) | 0.015% max |
B16 mechanical properties are diameter-dependent: strength is highest in smaller diameters and tapers as diameter increases. The primary specification (up to 2-1/2 inch) is the headline a buyer needs; the larger-diameter values follow.
| Property | Up to 2-1/2 in (M64) | Over 2-1/2 to 4 in (M64-M100) | Over 4 to 7 in (M100-M180) |
|---|---|---|---|
| Tensile strength, min | 860 MPa (125 ksi) | 760 MPa (110 ksi) | 690 MPa (100 ksi) |
| Yield strength, min | 725 MPa (105 ksi) | 655 MPa (95 ksi) | 585 MPa (85 ksi) |
| Elongation, min | 18% | 17% | 16% |
| Reduction of area, min | 50% | 45% | 45% |
| Hardness, max | 35 HRC (321 HBW) | 35 HRC (321 HBW) | 35 HRC (321 HBW) |
| Standard | Equivalent Grade | Region |
|---|---|---|
| ASTM A193 B16 | 1.7711 / 25CrMo4 | DIN / EN (Europe) |
| ASTM A193 B16 | SCM435 | JIS (Japan) |
| ASTM A193 B16 | 34CrMo4 | ISO |
| ASTM A193 B16 | SNB16 | KS (Korea) |
| ASTM A193 B16 | AISI 4140 (V-modified) | AISI (USA) |
| Item | Detail |
|---|---|
| Raw material | Chromium-Molybdenum-Vanadium alloy steel, quenched & tempered |
| Specification | ASTM A193 / ASME SA193 |
| Length | 3 mm to 200 mm |
| Size | 3/8 in to 2 in, M3 to M56, custom sizes |
B16 fasteners are produced to international dimensional standards for hex bolts, stud bolts, nuts, socket cap screws, set screws, countersunk screws, studs, and washers. Pair B16 bolts with A194 Grade 7 nuts as standard.
| Hexagon Bolt / Set Screws | Stud Bolt | Hexagon Nuts | Socket Cap screws |
|---|---|---|---|
| DIN 931 | BS4882 | DIN 934 | DIN 912 |
| DIN 933 | DIN 976 | BS 1768 | DIN 6912 |
| BS 1768 | BS 1769 | DIN 7984 | |
| UNI 5731 | BS 1083 | ANSI B18.3 | |
| UNI 5739 | BS 3692 | ISO 4762 | |
| ISO 4014 | ISO 4032 | UNI 5931 | |
| ISO 4017 | ISO 4033 | BS 2470 | |
| BS 1769 | ANSI B18.2.2 | BS 4168 | |
| BS 3692 | |||
| ANSI B18.2.1 |
| Socket & Slotted Set Screws | Socket & Slotted Countersunk Screws | Studs | Washers |
|---|---|---|---|
| DIN 913 | DIN 963 | DIN 938 | DIN 125 |
| DIN 914 | DIN 7991 | DIN 939 | DIN 9021 |
B16's high-temperature creep resistance sends it to the hottest bolted joints in heavy industry, the applications where B7 would relax and leak:
Unifit Fastener manufactures ASTM A193 B16 fasteners in India and exports to high-temperature process industries worldwide, across the Middle East, Southeast Asia, Europe, North America, and Africa. Every order ships with EN 10204 3.1 mill test certification, PMI on request, and full heat-number traceability, with export documentation and third-party inspection handled in-house. For a price or custom quote, send your size, quantity, and specification.
ASTM A193 Grade B16 is a chromium-molybdenum-vanadium (Cr-Mo-V) alloy steel for high-temperature, high-pressure bolting. The vanadium addition and higher tempering temperature give it strong resistance to creep and stress relaxation, so it holds bolt preload at temperatures up to about 590 C (1100 F), well beyond Grade B7.
Both are quenched-and-tempered chromium-molybdenum steels with similar room-temperature strength. B16 adds vanadium and is tempered higher, which resists stress relaxation at elevated temperature. Below about 400 C, B7 is the economical default; above it, B16 holds clamping force where B7 would creep and let the joint leak.
Common equivalents include 25CrMo4 / 1.7711 (DIN/EN), SCM435 (JIS), 34CrMo4 (ISO), and SNB16 (KS). The closest AISI base is 4140 modified with vanadium. Equivalents match the Cr-Mo-V chemistry and elevated-temperature strength rather than being identical.
Pair B16 bolts and studs with ASTM A194 Grade 7 nuts, which have matching high-temperature properties, and Grade 16 nuts for the very hottest service. Do not use standard 2H nuts, whose temperature capability does not match the bolt.
B16 holds usable mechanical properties and creep resistance to approximately 590 C (1100 F). Above that range, stainless (A193 B8 class) or nickel-alloy bolting is specified. Note that like all A193 alloy grades, B16 is not intended for cryogenic service, where A320 L7 is used instead.
Send your grade, size, quantity, and standard, or your drawing for custom B16 fasteners, and we will confirm availability, certification, and lead time for domestic supply or export.
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